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They will continue to rust, no matter what you coat them with, if you don't stop the pin from rubbing (what ever rust preventing coating) off on the female part. Seems like everything these days is made from cheap Chinese steel (low Ni content) that will rust like crazy if exposed just a little, and that doesn't help. You could get them chrome plated, but you still need something to protect the pin surface from rubbing/scratching it off.
You could only get them anodized if they were Aluminum (which is what you should do, and these are obviously not Al, hence rust).
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